By Kenneth D. Karlin

Growth in Inorganic Chemistry maintains in its culture of being the main revered discussion board for changing leading edge study. This sequence offers inorganic chemists and fabrics scientists with a neighborhood the place severe, authoritative reviews of advances in each sector of the self-discipline are exchanged. With contributions from across the world popular chemists, this newest quantity bargains an in-depth, far-ranging exam of the altering face of the sphere, offering a tantalizing glimpse of the rising kingdom of the technology.

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J. Vogel, J. Biol. Inorg. , 1, 39–48 (1996). ] FUNDAMENTAL CHEMISTRY OF LEAD(II) H. 35 Spectroscopy Conclusions Taken together, the studies that have been conducted to date on the absorption, photoelectron, vibrational, and NMR spectra of Pb(II) compounds suggest that divalent lead is far from ‘‘spectroscopically silent’’. These studies have provided useful insights into the electronic structure of Pb(II) compounds and the role that relativistic effects play in determining the properties of Pb(II).

39, 1391–1397 (2000). ] sensitive to the type of donor atoms surrounding the lead ion (Fig. 8) (39). , proteins). 1. Lead-207 Parameters: Chemical Shifts and Coupling Constants The lead chemical shift provides an excellent measure of the type of donor atoms bound to lead. As in other heavy metal NMR spectroscopies (e. , 113Cd, 199 Hg) (184, 185), the 207Pb resonances become more deshielded and shift downfield as the electronegativity of the donor atom decreases—opposite the effect observed in 1H NMR spectroscopy (186, 187).

3. Lead-207 NMR Spectroscopy of Proteins The first application of 207Pb NMR spectroscopy to metalloproteins was reported relatively recently by Vogel and co-workers (173), who used this Figure 9. (Continued) 34 ELIZABETH S. CLAUDIO ET AL. technique to study lead binding to a series of calcium proteins, including calmodulin. The sensitivity of 207Pb chemical shifts to the local chemical environment can be seen from the addition of 207Pb(II) to apo-calmodulin: Although the chemical environments of the four metal-binding sites in calmodulin are extremely similar, four distinct 207Pb resonances are observed (Fig.

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